Multidentate fluorinated alkoxide ligand platforms for oxophilic metal centers: from MOCVD source reagents to polymerizationcatalysts
نویسندگان
چکیده
منابع مشابه
Three-coordinate late transition metal fluorinated alkoxide complexes.
Homoleptic fluorinated alkoxide complexes have been prepared from KOC4F9, 1, via salt metathesis routes. One four-coordinate K{K(18C6)}[Co(OC4F9)4], 2, and four three-coordinate complexes: {K(18C6)}[Fe(OC4F9)3], 3, {K(18C6)}[Co(OC4F9)3], 4, {K(18C6)}[Cu(OC4F9)3], 5, and {K(18C6)}[Zn(OC4F9)3], 6, have been prepared and all except 5 have been characterized crystallographically. Compounds 3, 4, an...
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Bismuth oxide (Bi2O3) is an important component of several ferroelectric, 1 multiferroic 2,3 and superconducting oxide materials. 4 It has also received much interest due to its use as an ion conducting electrolyte material in solid oxide fuel cells, 5 an electrode material in discriminating gas sensors 6 and as an effective UV light photocatalyst. 7,8 There are a number of distinct crystallogr...
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The partially fluorinated oxo-alkoxide tungsten(VI) complexes WO(OR)4 [4; R = C(CH3)2CF3, 5; R = C(CH3)(CF3)2] have been synthesized as precursors for chemical vapour deposition (CVD) of WOx nanocrystalline material. Complexes 4 and 5 were prepared by salt metathesis between sodium salts of the fluoroalkoxides and WOCl4. Crystallographic structure analysis allows comparison of the bonding in 4 ...
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ژورنال
عنوان ژورنال: Dalton Trans.
سال: 2010
ISSN: 1477-9226,1477-9234
DOI: 10.1039/b915172a